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Why can rubber products maintain good corrosion resistance in a variety of media?

Publish Time: 2025-07-08
In modern industrial environments, many equipment and components are exposed to oils, acid and alkali solutions, solvents and other corrosive chemical media for a long time. In this context, rubber products are widely used in chemical, automotive, medical, aerospace and other fields due to their excellent chemical corrosion resistance.

1. Designability of molecular structure: the key to adapting to different media

In traditional cognition, rubber is a natural or synthetic polymer material, but modern rubber products are no longer composed of a single component. By changing the polymer main chain structure, introducing specific functional groups or using copolymerization modification technology, engineers can customize the rubber formula according to the properties of the target medium. For example, when facing petroleum-based lubricants, the use of nitrile rubber (NBR) with a high acrylonitrile content can significantly improve its anti-swelling ability; in strong acid environments, fluororubber (FKM) is selected because the fluorine element contained in its main chain greatly enhances its resistance to acidic substances.

This "custom-made" material design concept enables rubber products to maintain a low volume expansion rate and mechanical property loss in different media, thereby avoiding early failure caused by media erosion.

2. Cross-linking density regulation: improving chemical penetration resistance

The cross-linking structure of rubber determines the density of its internal network. Generally speaking, the higher the cross-linking density, the stronger the permeability and swelling resistance of the rubber. Therefore, during the manufacturing process, technicians will adjust the vulcanization system and the type of cross-linking agent according to the actual application requirements to control the cross-linking density. For example, in the case of contact with organic solvents, appropriately increasing the number of cross-linking points can effectively reduce the penetration of solvent molecules and reduce the risk of swelling and deformation of the material.

In addition, some high-performance rubbers also use disulfide bonds or polysulfide bonds for cross-linking, which not only improves heat resistance, but also enhances resistance to oxidizing media. This structural optimization provides an important guarantee for the stable performance of rubber products in complex media.

3. Application of functional additives: building multiple protective barriers

In addition to basic polymers and cross-linked structures, rubber products often contain a variety of functional additives, such as antioxidants, antioxidants, flame retardants, and special filling materials. The role of these additives is not only to improve processing performance, but more importantly, they can form a protective layer on the surface or inside of the rubber, further enhancing its ability to resist chemical erosion.

For example, when facing strong acid or alkaline media, adding an appropriate amount of metal oxide fillers (such as magnesium oxide and zinc oxide) can neutralize some acidic or alkaline substances and reduce their damage to the rubber body. In oil environments, some polar plasticizers can synergize with rubber molecules to prevent oil from penetrating and destroying its original structure.

4. Development of surface treatment technology: from passive protection to active defense

In recent years, with the development of materials science, the surface treatment technology of rubber products has also made great progress. Traditional rubber products mainly rely on the material itself to resist medium erosion, but now more and more manufacturers are beginning to use advanced processes such as plasma treatment, coating deposition, and nano-encapsulation to functionalize the rubber surface.

For example, by coating a layer of silane coupling agent or fluorocarbon resin on the rubber surface, its surface energy can be effectively reduced, and its affinity for liquid media can be greatly reduced, thereby reducing liquid adsorption and penetration. For another example, by using plasma-induced grafting technology, functional groups with anti-corrosion properties can be introduced on the rubber surface, so that it has stronger "self-cleaning" ability and chemical inertness when in contact with corrosive media.

In summary, the reason why rubber products can maintain good corrosion resistance in a variety of media is not only dependent on its original material properties, but is achieved through the synergistic effects of molecular structure design, cross-linking network optimization, functional additive addition, and surface engineering technology. It is the continuous integration of these innovative means that enables rubber products to maintain stable performance in extreme chemical environments and become an indispensable and important material in many industries.
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